Ryskulova, Kanykei published the artcileEffect of Host-Guest Complexation on the Thermoresponsive Behavior of Poly(oligo ethylene glycol acrylate)s Functionalized with Dialkoxynaphththalene Guest Side Chains, Name: 2,5,8,11-Tetraoxatridecan-13-ol, the main research area is host guest complexation thermoresponsive behavior polyoligoethyleneglycol acrylate functionalized dialkoxynaphththalene; LCST; host-guest complexation; responsive polymers; supramolecular chemistry.
The combination of thermoresponsive polymers with supramol. host-guest interactions enables accurate tuning of the phase transition temperature, while also providing addnl. response mechanisms based on host-guest complexation. Most studies focused on a single thermoresponsive polymer to demonstrate the effect of host-guest complexation on the responsive behavior. In this work, the effect of the polymer structure on the host-guest complexation and thermoresponsive behavior is reported. Therefore, different poly(oligoethylene glycol acrylate)s, namely, poly(2-hydroxyethylacrylate) (PHEA), poly(methoxy diethylene glycol acrylate), poly(methoxy triethylene glycol acrylate), and poly(methoxy tetraethylene glycol acrylate), are synthesized functionalized with 1,5-dialkoxynaphthalene guest mols. in the side chain. Their complexation with the cyclobis(paraquat-p-phenylene) tetrachloride host is studied to understand the effect of polymer structure on the supramol. association and the polymer phase transition, revealing that the oligoethylene glycol side chains lead to weaker host-guest complexation and also have a smaller increase in the cloud point temperature compared to PHEA.
Macromolecular Rapid Communications published new progress about Binding energy. 23783-42-8 belongs to class ethers-buliding-blocks, name is 2,5,8,11-Tetraoxatridecan-13-ol, and the molecular formula is C9H20O5, Name: 2,5,8,11-Tetraoxatridecan-13-ol.
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem