Smith, Amos B. III’s team published research in Organic Letters in 10 | CAS: 99438-28-5

Organic Letters published new progress about 99438-28-5. 99438-28-5 belongs to ethers-buliding-blocks, auxiliary class Chiral,Aliphatic cyclic hydrocarbon, name is (+)-B-Methoxydiisopinocampheylborane, and the molecular formula is C5H10O, Synthetic Route of 99438-28-5.

Smith, Amos B. III published the artcileTotal Synthesis of (-)-2-epi-Peloruside A, Synthetic Route of 99438-28-5, the publication is Organic Letters (2008), 10(24), 5501-5504, database is CAplus and MEDLINE.

A convergent synthesis of (-)-2-epi-peloruside A has been achieved. Highlights include implementation of multi-component type I anion relay chem. (ARC) to unite 2-TBS-1,3-dithiane with two epoxides to construct the eastern hemisphere, a late-stage dithiane union to secure the complete, fully functionalized carbon backbone, and Yamaguchi macrolactonization, which led to (-)-2-epi-peloruside A via an unexpected epimerization at C(2).

Organic Letters published new progress about 99438-28-5. 99438-28-5 belongs to ethers-buliding-blocks, auxiliary class Chiral,Aliphatic cyclic hydrocarbon, name is (+)-B-Methoxydiisopinocampheylborane, and the molecular formula is C5H10O, Synthetic Route of 99438-28-5.

Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem