Rozas, Robinson published the artcileSolvent effects on the molecular structure of isolated lignins of Eucalyptus nitens wood and oxidative depolymerization to phenolic chemicals, Synthetic Route of 134-96-3, the publication is Polymer Degradation and Stability (2022), 109973, database is CAplus.
The aim of the present work was to study the effect of a solvent/water mixture on the structural characteristics of extracted lignin from Eucalyptus nitens, and to relate the functional groups and inter unit linkages present in the lignin with the distribution of phenolic compounds obtained after its alk. oxidation The high content of β-O-4′ substructures linked to a S unit in organosolv lignins of E. nitens lignin could be linked to the high yield of syringaldehyde in its alk. oxidation Kraft lignin oxidation gives rise to lower content of syringaldehyde when compared with organosolv lignins. This might be due to the higher proportion of condensed structures, mainly β-β’ (∼42%) and spirodienone (∼14%). Fukui functions showed that the regions with higher probability for an electrophilic attack on lignin would be located on Ph rings and on the phenolic -OH group (benzylic position), whereas nucleophilic attacks in some cases were located over the double bond and ring. This work contributed to a better description of the proposed oxidative depolymerization mechanisms.
Polymer Degradation and Stability published new progress about 134-96-3. 134-96-3 belongs to ethers-buliding-blocks, auxiliary class Immunology/Inflammation,COX,Natural product, name is 4-Hydroxy-3,5-dimethoxybenzaldehyde, and the molecular formula is C9H10O4, Synthetic Route of 134-96-3.
Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem