Ferrando, German published the artcileFacile C(sp2)/OR bond cleavage by Ru or Os, Product Details of C8H9ClO, the main research area is osmium phosphine olefin complex DFT; ruthenium phosphine olefin complex DFT; crystal structure osmium phosphine carbyne complex preparation; mol structure osmium phosphine carbyne complex; isomerization osmium phosphine carbene complex kinetics; olefin osmium ruthenium complex preparation isomerization carbene; carbyne osmium complex preparation DFT; vinylidene osmium ruthenium complex preparation DFT.
Os(H)3ClL2 (L = PiPr3 or PtBu2Me) are shown to be useful “”precursors”” to “”OsHClL2″”, which react with vinyl ethers to form first an η2-olefin adduct and then isomerize to the carbenes, OsHCl[CMe(OR)]L2. Subsequent R- and L-dependent reactions involve C(sp2)-OR bond cleavage, to make either carbyne or vinylidene complexes. The mechanisms of these reactions are explored, and the thermodn. disparity of Ru vs. Os and the influence of the OR group and the spectator phosphine ligands are discussed based on DFT (B3PW91) calculations
Inorganic Chemistry published new progress about C-O bond cleavage. 622-86-6 belongs to class ethers-buliding-blocks, name is (2-Chloroethoxy)benzene, and the molecular formula is C8H9ClO, Product Details of C8H9ClO.
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem