Hypervalent Iodine(III) in Direct Oxidative Amination of Arenes with Heteroaromatic Amines was written by Manna, Srimanta;Serebrennikova, Polina O.;Utepova, Irina A.;Antonchick, Andrey P.;Chupakhin, Oleg N.. And the article was included in Organic Letters in 2015.Reference of 562085-85-2 The following contents are mentioned in the article:
A novel, mild, and practical method of amination of simple nonfunctionalized arenes under metal free conditions has been developed. The approach allows coupling of electron-rich arenes with amino derivatives of electron-deficient heterocycles providing rapid access to scaffolds of bioactive compounds and is based on the application of the hypervalent iodine(III) reagent as an oxidant. Regioselective functionalization of C-H bonds of arenes by the formation of C-N bonds under organocatalytic conditions was demonstrated. This study involved multiple reactions and reactants, such as N-(4-Methoxyphenyl)pyridin-3-amine (cas: 562085-85-2Reference of 562085-85-2).
N-(4-Methoxyphenyl)pyridin-3-amine (cas: 562085-85-2) belongs to ethers. Volatile esters with characteristic odours are used in synthetic flavours, perfumes, and cosmetics. Certain volatile esters are used as solvents for lacquers, paints, and varnishes. Because of their lack of hydrogen-bond-donating ability, esters do not self-associate. Consequently, esters are more volatile than carboxylic acids of similar molecular weight.Reference of 562085-85-2
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem