A versatile catalyst-free redox system mediated by carbon dioxide radical and dimsyl anions was written by Huang, Yan;Zhang, Qian;Hua, Li-Li;Zhan, Le-Wu;Hou, Jing;Li, Bin-Dong. And the article was included in Cell Reports Physical Science in 2022.Quality Control of 2-Methoxyethylamine The following contents are mentioned in the article:
A redox system mediated by carbon dioxide radical and dimsyl anions was demonstrated and a variety of transformations, including hydrocarboxylation, hydroxycarboxylation, Birch reduction and three-component reductive coupling of carbonyl compounds, amines and cyanopyridine were achieved in a catalyst-free fashion using this method, giving valuable acids, saturated skeletons and α-pyridyl amines in high efficiency. This strategy promises wide applications in other types of reactions and complements current photoredox catalysis methodologies. This study involved multiple reactions and reactants, such as 2-Methoxyethylamine (cas: 109-85-3Quality Control of 2-Methoxyethylamine).
2-Methoxyethylamine (cas: 109-85-3) belongs to ethers. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. Because of their lack of hydrogen-bond-donating ability, esters do not self-associate. Consequently, esters are more volatile than carboxylic acids of similar molecular weight.Quality Control of 2-Methoxyethylamine
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem