Catalyst-free reductive hydrogenation or deuteration of aryl-heteroatom bonds induced by light was written by Yan, Boyu;Zhou, Yutong;Wu, Jieliang;Ran, Maogang;Li, Huihui;Yao, Qiuli. And the article was included in Organic Chemistry Frontiers in 2021.Application of 103-16-2 The following contents are mentioned in the article:
A simple and catalyst-free photochem. strategy for the direct reduction of aryl trimethylammonium salts ArNMe3OTf (Ar = biphenyl-4-yl, 2-naphthyl, quinolin-3-yl, etc.), aryl triflates Ar1OTf (Ar1 = biphenyl-3-yl, 1,6-dimethylpyridin-4-yl, benzothiazol-5-yl, etc.), and haloarenes Ar2X (Ar2 = biphenyl-4-yl, 2-naphthyl, quinolin-4-yl, etc.; X = Cl, Br, I) to arenes ArH/Ar1H or deuterium-labeled arenes ArD/Ar1D/Ar2D was described. A broad range of substrate scope was demonstrated with high yields and deuterium incorporations. Radical clock experiments indicate the formation of aryl radical intermediates that can also be trapped by phenols. This study involved multiple reactions and reactants, such as 4-Benzyloxyphenol (cas: 103-16-2Application of 103-16-2).
4-Benzyloxyphenol (cas: 103-16-2) belongs to ethers. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits, including apples, durians, pears, bananas, pineapples, and strawberries. Because of their lack of hydrogen-bond-donating ability, esters do not self-associate. Consequently, esters are more volatile than carboxylic acids of similar molecular weight.Application of 103-16-2
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem