On January 31, 2022, Fang, Jing; Li, Ting; Ma, Xiang; Sun, Jiuchang; Cai, Lei; Chen, Qi; Liao, Zhiwen; Meng, Lingkui; Zeng, Jing; Wan, Qian published an article.COA of Formula: C13H11BrS The title of the article was Discriminating non-ylidic carbon-sulfur bond cleavages of sulfonium ylides for alkylation and arylation reactions. And the article contained the following:
A sulfonium ylide participated alkylation and arylation under transition-metal free conditions was described. The disparate reaction pattern allowed the sep. activation of non-ylidic S-alkyl and S-aryl bond. Under acidic conditions, sulfonium ylides served as alkyl cation precursors which facilitated the alkylations. While under alk. conditions, cleavage of non-ylidic S-aryl bond produces O-arylated compounds efficiently. The robustness of the protocols were established by the excellent compatibility of wide variety of substrates including carbohydrates. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).COA of Formula: C13H11BrS
The Article related to sulfonium ylide preparation alkylation arylation, General Organic Chemistry: Synthetic Methods and other aspects.COA of Formula: C13H11BrS
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