On May 27, 2022, Scattolin, Thomas; Gharbaoui, Tawfik; Chen, Cheng-yi published an article.Synthetic Route of 53136-21-3 The title of the article was A Nucleophilic Deprotection of Carbamate Mediated by 2-Mercaptoethanol. And the article contained the following:
Carbamates, typically used for the protection of amines, including Cbz, Alloc, and Me carbamate, was readily deprotected by treatment with 2-mercaptoethanol in the presence of potassium phosphate tribasic in N,N-dimethylacetamide at 75°C. This nucleophilic deprotection protocol was superior to the standard hydrogenolysis or Lewis acid-mediated deprotection conditions for substrates bearing a functionality sensitive to these more traditional methods. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Synthetic Route of 53136-21-3
The Article related to carbamate mercaptoethanol nucleophilic deprotection, secondary amine preparation, General Organic Chemistry: Synthetic Methods and other aspects.Synthetic Route of 53136-21-3
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