Spencer, Andrew R. A.; Korde, Rishi; Font, Marc; Larrosa, Igor published an article in 2020, the title of the article was meta-Selective olefination of fluoroarenes with alkynes using CO2 as a traceless directing group.Computed Properties of 321-28-8 And the article contains the following content:
Herein, it is reported that meta-selective olefination of fluoroarenes can be achieved via the use of CO2 as a traceless directing group, which can be easily installed and removed in a one-pot process. Furthermore, this approach avoids the use of stoichiometric Ag(I)-salts, commonly used in C-H olefinations, and affords complete meta- over ortho/para-regioselectivity. The experimental process involved the reaction of 1-Fluoro-2-methoxybenzene(cas: 321-28-8).Computed Properties of 321-28-8
The Article related to fluoroarene alkyne meta olefination diastereoselective regioselective ruthenium catalyst, carbon dioxide directing group, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Halides and Halonium Compounds and other aspects.Computed Properties of 321-28-8
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem