Wu, Yaxing; Ding, Hongliang; Zhao, Ming; Ni, Zhong-Hai; Cao, Jing-Pei published an article in 2020, the title of the article was Electrochemical and direct C-H methylthiolation of electron-rich aromatics.Synthetic Route of 93-04-9 And the article contains the following content:
The electrochem.-induced C-H methylthiolation of electron-rich aromatics for the synthesis of thiomethylated aromatics ArSR [R = Me, Et, n-Pr; Ar = 4-MeOC6H4, 4-MeNHC6H4, 2-MeO-1-naphthyl, etc.] was accomplished via a three component cross-coupling strategy. Potassium thiocyanate (KSCN) as both the supporting electrolyte and sulfur source and methanol as the methylation reagent were used. This protocol was versatile for various (hetero)aromatic compounds such as aniline, anisole and indole. The reaction proceeded under mild conditions without any metal catalyst, exogenous oxidant and highly toxic sulfur reagent. Importantly, such an electrochem.-induced methylthiolated reaction could be easily scaled up with good efficiency. The experimental process involved the reaction of 2-Methoxynaphthalene(cas: 93-04-9).Synthetic Route of 93-04-9
The Article related to thiomethylated aromatic compound preparation, electron rich aromatic compound electrochem methylthiolation, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Hydrocarbons (Saturated and Unsaturated Side Chains) and other aspects.Synthetic Route of 93-04-9
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