On June 4, 2021, Zhang, Qiaoling; Feng, Hang; Chen, Feng; He, Ze; Zeng, Qingle published an article.Computed Properties of 53136-21-3 The title of the article was Unusual Deoxidative Coupling Reaction of β-Sulfinyl Esters with Benzylic Trimethylammonium Salts. And the article contained the following:
A KOH-promoted unusual deoxidative coupling reaction of β-sulfinyl esters RS(O)(CH2)2C(O)2C(CH3)3 (R = 4-CH3C6H4, 2-pyridyl, 1H-1,3-benzodiazol-2-yl, etc.) with benzylic trimethylammonium salts ArN+(CH3)3-OTf (Ar = Bn, pyridin-2-ylmethyl, 1,2,3,4-tetrahydronaphthalen-1-yl, etc.) to produce thioethers RSAr is discovered for the first time. If quaternary ammonium salts synthesized from enantiomerically enriched amines are adopted, highly enantiomerically enriched benzyl thioethers (>95-99% ee) with configurations opposite to those of the enantiomerically enriched amines are obtained. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Computed Properties of 53136-21-3
The Article related to thioether preparation, sulfinyl ester benzylic trimethylammonium salt deoxidative coupling reaction, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Ethers, Sulfides, and The Corresponding Onium Compounds and other aspects.Computed Properties of 53136-21-3
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem