Lu, Fangling; Chen, Ziyue; Li, Zhen; Wang, Xiaoyan; Peng, Xinyue; Li, Cong; Li, Ru; Pei, Hongqiao; Wang, Huamin; Gao, Meng published an article in 2018, the title of the article was Copper-catalyzed alkylation of thiophenols with benzyltrimethylammonium triflates.Product Details of 53136-21-3 And the article contains the following content:
A copper-catalyzed cross coupling of thiophenols with benzyltrimethylammonium triflates was developed. Various kinds of aryl and heteroaryl thiophenols and alkylthiols demonstrated to be efficient substrates, generating the desired alkyl thioethers RSCH2R1 [R = 4-MeC6H4, CH2C6H5, 2-naphthyl, etc.; R1 = Ph, 2-MeC6H4, 4-BrC6H4, etc.] in moderate to good yields. Meanwhile, different benzyltrimethylammonium triflates could be well tolerated. Selected thioether products were further transformed into sulfoxide R2S(O)R3 [R2 = 4-MeC6H4, 4-ClC6H4, 4-BrC6H4, etc.; R3 = Ph, 4-MeC6H4, 2-IC6H4, etc.] with good efficiency. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Product Details of 53136-21-3
The Article related to aryl benzyl sulfoxide preparation, alkyl thioether reactant aryl benzyl sulfoxide preparation, thiophenol benzyltrimethylammonium triflate copper catalyst cross coupling alkylation and other aspects.Product Details of 53136-21-3
Referemce:
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Ether | (C2H5)2O – PubChem