Taglang, Celine; Martinez-Prieto, Luis Miguel; del Rosal, Iker; Maron, Laurent; Poteau, Romuald; Philippot, Karine; Chaudret, Bruno; Perato, Serge; Sam Lone, Anais; Puente, Celine; Dugave, Christophe; Rousseau, Bernard; Pieters, Gregory published an article in 2015, the title of the article was Enantiospecific C-H activation using ruthenium nanocatalysts.Safety of (S)-1-Methoxypropan-2-amine hydrochloride And the article contains the following content:
The activation of C-H bonds has revolutionized modern synthetic chem. However, no general strategy for enantiospecific C-H activation has been developed to date. We herein report an enantiospecific C-H activation reaction followed by deuterium incorporation at stereogenic centers. Mechanistic studies suggest that the selectivity for the α-position of the directing heteroatom results from a four-membered dimetallacycle as the key intermediate. This work paves the way to novel mol. chem. on nanoparticles. The experimental process involved the reaction of (S)-1-Methoxypropan-2-amine hydrochloride(cas: 1162054-86-5).Safety of (S)-1-Methoxypropan-2-amine hydrochloride
The Article related to enantiospecific ch activation reaction deuterium incorporation ruthenium nanocatalyst nanoparticle, langmuir hinshelwood deuteration mechanism ab initio dimetallacycle, ch activation, ab initio calculations, deuterium, isotopic labeling, nanoparticles and other aspects.Safety of (S)-1-Methoxypropan-2-amine hydrochloride
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem