Ethers feature bent C–O–C linkages. In dimethyl ether, the bond angle is 111° and C–O distances are 141 pm. 38256-93-8, formula is C4H11NO, Name is 2-Methoxy-N-methylethanamine. The barrier to rotation about the C–O bonds is low. The bonding of oxygen in ethers, alcohols, and water is similar. In the language of valence bond theory, the hybridization at oxygen is sp3. Related Products of 38256-93-8.
Lang, Simon B.;Wiles, Rebecca J.;Kelly, Christopher B.;Molander, Gary A. research published ã?Photoredox Generation of Carbon-Centered Radicals Enables the Construction of 1,1-Difluoroalkene Carbonyl Mimicsã? the research content is summarized as follows. 1,1-Disubstituted trifluoromethylalkenes such as I underwent photochem. alkylation and defluorination with aminomethylsilanes such as 4-(trimethylsilylmethyl)thiomorpholine, potassium trifluoroborates such as t-BuBF3–K+, or bis(catecholate)silicates in the presence of either a tetrakis(carbazolyl)benzenedicarbonitrile photocatalyst or Ru(bpy)3(PF6)2 in either DMF or DMSO under blue LED irradiation to yield difluoroalkenes such as II [R = 4-thiomorpholinyl, t-Bu, MeO(CH2)3]. Nonstabilized primary, secondary, and tertiary radicals generated from silanes, trifluoroborates, or silicates were used to install functional groups which would otherwise be challenging or would require extended syntheses using two-electron pathways. Difluoromethyl and pentafluoroethyl alkenes underwent analogous photochem. defluorinative alkylations to yield fluoroalkenes and trifluoromethylfluoroalkenes, resp. The trifluoropropenyltrifluoroborate reagent F3CC(:CH2)BF3–K+ was prepared as a convenient reagent for the preparation of trifluoromethyl alkenes amenable to defluorinative alkylation sequences.
Related Products of 38256-93-8, 2-Methoxy-N-methylethanamine is a useful research compound. Its molecular formula is C4H11NO and its molecular weight is 89.14 g/mol. The purity is usually 95%.
2-Methoxy-N-methylethanamine is a drug that binds to the cannabinoid receptor CB1. It has been shown to be effective in the treatment of cardiac arrhythmia and may also be used as an anti-inflammatory drug. 2MEMEA has been shown to have pharmacokinetic properties that are different from those of other amines, which may be due to its ability to form hydrogen bonds with water molecules. 2MEMEA also has diversified effects on some types of cancer cells, including hyperproliferative and amine-dependent cancers., 38256-93-8.
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem