In 2019,Organic Letters included an article by Chen, Yuye; Hu, Jingping; Guo, Lian-Dong; Tian, Peilin; Xu, Tianyue; Xu, Jing. Related Products of 60656-87-3. The article was titled 《Synthesis of the Core Structure of Daphnimacropodines》. The information in the text is summarized as follows:
Daphniphyllum alkaloids daphnimacropodines A-C possess a highly congested ring system and share a common tetracyclic ring skeleton. To access the challenging chem. structure of daphnimacropodines, a divergent synthetic approach toward their total synthesis is described. A stereoselective synthesis of the core structure I of daphnimacropodines has been achieved from a simple diketone building block. Our approach features an intramol. carbamate aza-Michael addition and a hydropyrrole synthesis via a Au-catalyzed alkyne hydration followed by an aldol condensation, whereas all the other attempts failed.2-(Benzyloxy)acetaldehyde(cas: 60656-87-3Related Products of 60656-87-3) was used in this study.
2-(Benzyloxy)acetaldehyde(cas: 60656-87-3) may be used in the following syntheses: (3S,5S)-methyl 6-benzyloxy-3,5-dihydroxyhexanoate ,(S)-5-benzyloxy-4-hydroxypentan-2-one, myxothiazols.Related Products of 60656-87-3
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem