《Modular bismacycles for the selective C-H arylation of phenols and naphthols》 was written by Jurrat, Mark; Maggi, Lorenzo; Lewis, William; Ball, Liam T.. Product Details of 150-19-6 And the article was included in Nature Chemistry in 2020. The article conveys some information:
Given the important role played by 2-hydroxybiaryls in organic, medicinal and materials chem., concise methods for the synthesis of this common motif are extremely valuable. In seeking to extend the lexicon of synthetic chemists in this regard, the authors have developed an expedient and general strategy for the ortho-arylation of phenols and naphthols using readily available boronic acids. The authors’ methodol. relies on in situ generation of a uniquely reactive Bi(V) arylating agent from a bench-stable Bi(III) precursor via telescoped B-to-Bi transmetalation and oxidation By exploiting reactivity that is orthogonal to conventional metal-catalyzed manifolds, diverse aryl and heteroaryl partners can be rapidly coupled to phenols and naphthols under mild conditions. Following arylation, high-yielding recovery of the Bi(III) precursor allows for its efficient re-use in subsequent reactions. Mechanistic interrogation of each key step of the methodol. informs its practical application and provides fundamental insight into the underexploited reactivity of organobismuth compounds In the part of experimental materials, we found many familiar compounds, such as m-Methoxyphenol(cas: 150-19-6Product Details of 150-19-6)
m-Methoxyphenol(cas: 150-19-6) may be used as an analytical standard for the determination of the analyte in wine, coffee beans, wood samples, and mainstream smoke by gas chromatography (GC) based techniques.Product Details of 150-19-6
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