《Open-Air Stereoselective Construction of C-Aryl Glycosides》 was published in Organic Letters in 2020. These research results belong to Lai, Mengnan; Othman, Karwan Abdulmajed; Yao, Hui; Wang, Qiuyuan; Feng, Yongkui; Huang, Nianyu; Liu, Mingguo; Zou, Kun. Safety of 3-Methoxyphenylboronic acid The article mentions the following:
A new methodol. of stereoselective C-glycosylation has been developed with 3,4-O-carbonate glycals and boronic acids, catalyzed by 1,2-bis(phenylsulfinyl)ethane palladium(II) acetate under open-air conditions at room temperature This mild method is simple in operation, wide in substrate range, and tolerant in alc./phenolic hydroxyl and amino groups. High to excellent yields were observed for all substrates tested, with the driving force mainly contributed by decarboxylation. Meanwhile, the high 1,4-trans-selectivity was achieved by steric effects as proposed. The experimental part of the paper was very detailed, including the reaction process of 3-Methoxyphenylboronic acid(cas: 10365-98-7Safety of 3-Methoxyphenylboronic acid)
3-Methoxyphenylboronic acid(cas: 10365-98-7) belongs to boronic acids. Boronic acids are mild Lewis acids which are generally stable and easy to handle, making them important to organic synthesis.Safety of 3-Methoxyphenylboronic acid
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem