Gao, Peng-Chao; Wang, Zi-Xuan; Li, Bi-Jie published their research in Organic Letters in 2021. The article was titled 《Iridium-Catalyzed Regioselective Hydroalkynylation of Internal Alkenes Directed by an Oxime》.Reference of 2-(Benzyloxy)acetaldehyde The article contains the following contents:
An iridium-catalyzed hydroalkynylation of allylic alcs. protected by an oxime group was reported. Catalytic alkynylation occurred exclusively at the distal position of the alkene. This method generated γ-alkynyl alc. oximes directly from internal alkenes and terminal alkynes. The oxime group was readily removed to afford a free alc., thus providing an indirect route for the catalytic hydroalkynylation of allylic alcs.2-(Benzyloxy)acetaldehyde(cas: 60656-87-3Reference of 2-(Benzyloxy)acetaldehyde) was used in this study.
2-(Benzyloxy)acetaldehyde(cas: 60656-87-3) may be used in the following syntheses: (3S,5S)-methyl 6-benzyloxy-3,5-dihydroxyhexanoate ,(S)-5-benzyloxy-4-hydroxypentan-2-one, myxothiazols.Reference of 2-(Benzyloxy)acetaldehyde
Referemce:
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Ether | (C2H5)2O – PubChem