Kawamoto, Takuji; Morioka, Tsubasa; Noguchi, Kohki; Curran, Dennis P.; Kamimura, Akio published an article in 2021. The article was titled 《Inverse Hydroboration of Imines with NHC-Boranes Is Promoted by Diphenyl Disulfide and Visible Light》, and you may find the article in Organic Letters.HPLC of Formula: 882-33-7 The information in the text is summarized as follows:
The authors describe a simple and efficient procedure for nucleophilic borylation of imines in the absence of a photoredox catalyst. Visible light irradiation of an MeCN solution of an imine, an NHC-borane, and di-Ph disulfide (10 mol %) provides various stable α-amino NHC-boranes in good yields. The reaction proceeds via addition of a nucleophilic boryl radical to an imine, followed by H abstraction from thiophenol, which is generated from NHC-borane and di-Ph disulfide. In the part of experimental materials, we found many familiar compounds, such as 1,2-Diphenyldisulfane(cas: 882-33-7HPLC of Formula: 882-33-7)
1,2-Diphenyldisulfane(cas: 882-33-7) belongs to ethers.The C-O bonds that comprise simple ethers are strong. HPLC of Formula: 882-33-7 They are unreactive toward all but the strongest bases. Although generally of low chemical reactivity, they are more reactive than alkanes.
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem