《Decarbonylative Suzuki-Miyaura Cross-Coupling of Aroyl Chlorides》 was published in Organic Letters in 2020. These research results belong to Zhou, Tongliang; Xie, Pei-Pei; Ji, Chong-Lei; Hong, Xin; Szostak, Michal. Name: 3-Methoxyphenylboronic acid The article mentions the following:
Herein, we report a catalyst system for Pd-catalyzed decarbonylative Suzuki-Miyaura cross-coupling of aroyl chlorides with boronic acids to furnish biaryls. This strategy is suitable for a broad range of common aroyl chlorides and boronic acids. The synthetic utility is highlighted in the direct late-stage functionalization of pharmaceuticals and natural products capitalizing on the presence of carboxylic acid moiety. Extensive mechanistic and DFT studies provide key insight into the reaction mechanism and high decarbonylative cross-coupling selectivity. In the experiment, the researchers used 3-Methoxyphenylboronic acid(cas: 10365-98-7Name: 3-Methoxyphenylboronic acid)
3-Methoxyphenylboronic acid(cas: 10365-98-7) belongs to boronic acids. Boronic acids are mild Lewis acids which are generally stable and easy to handle, making them important to organic synthesis.Name: 3-Methoxyphenylboronic acid
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