More, Sayaji Arjun; Kardile, Rahul Dadabhau; Kuo, Tung-Chun; Cheng, Mu-Jeng; Liu, Rai-Shung published their research in Organic Letters in 2021. The article was titled 《Gold Catalysts Can Generate Nitrone Intermediates from a Nitrosoarene/Alkene Mixture, Enabling Two Distinct Catalytic Reactions: A Nitroso-Activated Cycloheptatriene/Benzylidene Rearrangement》.Related Products of 2398-37-0 The article contains the following contents:
Gold-catalyzed reactions of cycloheptatrienes with nitrosoarenes yield nitrone derivatives efficiently. This reaction sequence enabled to develop gold-catalyzed aerobic oxidations of cycloheptatrienes to afford benzaldehyde derivatives using CuCl and nitrosoarenes as co-catalysts (10-30 mol %). D. functional theory calculations supported a novel nitroso-activated rearrangement, tropylium → benzylidene. With the same nitrosoarenes, gold-catalyzed [2 + 2 + 1]-annulations between nitrosobenzene and two enol ethers to yield 5-alkoxyisoxazolidines using 1,4-cyclohexadienes as hydrogen donors was developed. The experimental process involved the reaction of 1-Bromo-3-methoxybenzene(cas: 2398-37-0Related Products of 2398-37-0)
1-Bromo-3-methoxybenzene(cas: 2398-37-0) is a compound useful in organic synthesis and other chemical processes. It is an intermediate used for pharmaceuticals, perfumes and agrochemicals.Related Products of 2398-37-0
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem