Allylations of aryl/heteroaryl ketones: neat, clean and sustainable. Applications to targets in the pharma- and nutraceutical industries was written by Li, Xiaohan;Wood, Alex B.;Lee, Nicholas R.;Gallou, Fabrice;Lipshutz, Bruce H.. And the article was included in Green Chemistry in 2022.Quality Control of 2,3-Dimethoxy-5-methylcyclohexa-2,5-diene-1,4-dione This article mentions the following:
Aromatic and heteroaromatic ketones bearing an 濞?methine proton could be deprotonated and mono-allylated in minutes in the complete absence of an organic solvent to arrive at the corresponding allylated ketone products in high isolated yields. Applications to synthetic targets including both compounds I [n = 6, 8], as well as coenzyme II, utilizing this new technol. were documented. In the experiment, the researchers used many compounds, for example, 2,3-Dimethoxy-5-methylcyclohexa-2,5-diene-1,4-dione (cas: 605-94-7Quality Control of 2,3-Dimethoxy-5-methylcyclohexa-2,5-diene-1,4-dione).
2,3-Dimethoxy-5-methylcyclohexa-2,5-diene-1,4-dione (cas: 605-94-7) belongs to ethers. Of all the functional groups, ethers are the least reactive ones. Ether bonds are quite stable towards bases, oxidizing agents and reducing agents. Ethyl ether is an excellent solvent for extractions and for a wide variety of chemical reactions. It is also used as a volatile starting fluid for diesel engines and gasoline engines in cold weather. Dimethyl ether is used as a spray propellant and refrigerant. Methyl t-butyl ether (MTBE) is a gasoline additive that boosts the octane number and reduces the amount of nitrogen-oxide pollutants in the exhaust. The ethers of ethylene glycol are used as solvents and plasticizers.Quality Control of 2,3-Dimethoxy-5-methylcyclohexa-2,5-diene-1,4-dione
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem