Selective Reductive Cleavage of Inert Aryl C-O Bonds by an Iron Catalyst was written by Ren, Yunlai;Yan, Mengjie;Wang, Jianji;Zhang, Z. Conrad;Yao, Kaisheng. And the article was included in Angewandte Chemie, International Edition in 2013.Related Products of 75581-11-2 This article mentions the following:
An effective reductive cleavage of inert aryl C-O bonds with an inexpensive Fe catalyst has been developed. During this process, the reduction of the arene rings was not observed This catalytic system also enabled the selective cleavage of the 灏?O-4 linkage of lignin model compounds, thus offering an opportunity for the depolymerization of lignin. Thus, e.g., reductive cleavage of Ph2O in presence of Fe(acac)3, LiAlH4 as reducing agent, and tBuONa at 140鎺?afforded PhOH (81%) and benzene (97%). In the experiment, the researchers used many compounds, for example, 4-Iodo-1-methoxy-2-methylbenzene (cas: 75581-11-2Related Products of 75581-11-2).
4-Iodo-1-methoxy-2-methylbenzene (cas: 75581-11-2) belongs to ethers. Of all the functional groups, ethers are the least reactive ones. Ether bonds are quite stable towards bases, oxidizing agents and reducing agents. Ethers are good solvents partly because they are not very reactive. Most ethers can be cleaved, however, by hydrobromic acid (HBr) to give alkyl bromides or by hydroiodic acid (HI) to give alkyl iodides.Related Products of 75581-11-2
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem