Crystal structure of bis[4′-(1,4,7,10-tetraoxa-13- azacyclopentadecan-13-yl)-2,2′:6′,2”-terpyridine]cobalt(III) tris(perchlorate) methanol monosolvate monohydrate was written by Ohmagari, Hitomi;Nakaya, Manabu;Ohtani, Ryo;Nakamura, Masaaki;Hayami, Shinya. And the article was included in Acta Crystallographica, Section E: Crystallographic Communications in 2015.Recommanded Product: 1,4,7,10-Tetraoxa-13-azacyclopentadecane This article mentions the following:
In the title compound, [Co(C25H30N4O4)2](ClO4)3璺疌H3OH璺疕2O, the metal atom is coordinated by two tridentate crown ether terpyridine ligands, forming a distorted CoN6 octahedron. The three pyridine rings in each crown-terpyridine ligand are approx. coplanar [maximum deviations = 0.088 (12) and 0.102 (15) 鑴淽 and the mean planes through the three pyridine rings are perpendicular to each other, making a dihedral angle of 89.95 (17)鎺? An intramol. C-H璺矾璺熀 interaction is observed between the two terpyridine ligands. In the crystal, O-H璺矾璺疧 and C-H璺矾璺疧 hydrogen bonds, a 锜?锜?stacking interaction [centroid-centroid distance = 3.923 (7) 鑴淽 and a C-H璺矾璺熀 interaction connect the complex cation, the perchlorate anions and the two types of solvent mols., forming a three-dimensional network. In the experiment, the researchers used many compounds, for example, 1,4,7,10-Tetraoxa-13-azacyclopentadecane (cas: 66943-05-3Recommanded Product: 1,4,7,10-Tetraoxa-13-azacyclopentadecane).
1,4,7,10-Tetraoxa-13-azacyclopentadecane (cas: 66943-05-3) belongs to ethers. Ethers are good solvents partly because they are not very reactive. Most ethers can be cleaved, however, by hydrobromic acid (HBr) to give alkyl bromides or by hydroiodic acid (HI) to give alkyl iodides. Electron-deficient reagents are also stabilized by ethers. For example, borane (BH3) is a useful reagent for making alcohols. Pure borane exists as its dimer, diborane (B2H6), a toxic gas that is inconvenient and hazardous to use. Borane forms stable complexes with ethers, however, and it is often supplied and used as its liquid complex with tetrahydrofuran (THF).Recommanded Product: 1,4,7,10-Tetraoxa-13-azacyclopentadecane
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem