Ligand free copper-catalyzed heterogeneous O-arylation reaction under green condition was written by Maity, Tanmoy;Saha, Debraj;Das, Soma;Bhunia, Susmita;Koner, Subratanath. And the article was included in Catalysis Communications in 2015.Safety of 1-(4-(4-Methoxyphenoxy)phenyl)ethanone This article mentions the following:
A highly porous Zn-based iso-reticular metal-organic framework (IRMOF-3) has been selected for covalent modification. Pyridine-2-aldehyde has been used to decorate the free amine group of IRMOF-3 in the porous matrix. Schiff base moiety thus generated has been availed to anchor copper(II) ions to prepare the desired catalyst that catalyzes O-arylation reactions heterogeneously under mild reaction conditions. Porous catalyst demonstrates size selectivity in products when various substrates undergo O-arylation with 浼?and 灏?naphthol. In the experiment, the researchers used many compounds, for example, 1-(4-(4-Methoxyphenoxy)phenyl)ethanone (cas: 54916-28-8Safety of 1-(4-(4-Methoxyphenoxy)phenyl)ethanone).
1-(4-(4-Methoxyphenoxy)phenyl)ethanone (cas: 54916-28-8) belongs to ethers. Of all the functional groups, ethers are the least reactive ones. Ether bonds are quite stable towards bases, oxidizing agents and reducing agents. But on the other hand, ethers undergo cleavage by reaction with acids. At room temperature, ethers are pleasant-smelling colourless liquids. Relative to alcohols, ethers are generally less dense, are less soluble in water, and have lower boiling points. They are relatively unreactive, and as a result they are useful as solvents for fats, oils, waxes, perfumes, resins, dyes, gums, and hydrocarbons. Vapours of certain ethers are used as insecticides, miticides, and fumigants for soil.Safety of 1-(4-(4-Methoxyphenoxy)phenyl)ethanone
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem