Studies of photochemistry of aromatic hydrocarbons. III. Formation of nitrophenols by the photochemical reaction of toluene in the presence of nitrogen monoxide and nitrophenols in rain was written by Nojima, Kazuhiro;Fukaya, Katsuhisa;Fukui, Shozo;Kanno, Saburo;Nishiyama, Shinichi;Wada, Yutaka. And the article was included in Chemosphere in 1976.Safety of 3-Methyl-4-nitroanisole This article mentions the following:
Photoreaction of toluene with NO gives o-cresol, m-nitrotoluene, p-nitrophenol (I), 2-methyl-6-nitrophenol (II), 3-methyl-4-nitrophenol, 2-methyl-4-nitrophenol (III), and 2-methyl-4,6-dinitrophenol, all identified by gas chromatog.-mass spectrometry. Mass fragmentation anal. showed that I, II, and III are present in rain. In the experiment, the researchers used many compounds, for example, 3-Methyl-4-nitroanisole (cas: 5367-32-8Safety of 3-Methyl-4-nitroanisole).
3-Methyl-4-nitroanisole (cas: 5367-32-8) belongs to ethers. Of all the functional groups, ethers are the least reactive ones. Ether bonds are quite stable towards bases, oxidizing agents and reducing agents. At room temperature, ethers are pleasant-smelling colourless liquids. Relative to alcohols, ethers are generally less dense, are less soluble in water, and have lower boiling points. They are relatively unreactive, and as a result they are useful as solvents for fats, oils, waxes, perfumes, resins, dyes, gums, and hydrocarbons. Vapours of certain ethers are used as insecticides, miticides, and fumigants for soil.Safety of 3-Methyl-4-nitroanisole
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem