Solvation enthalpy of selected glymes in the mixtures of N,N-dimethylformamide with propan-1-ol or methanol at 298.15 K. The solvent contribution to the solvation enthalpy of glymes was written by Jozwiak, Malgorzata;Ludzik, Katarzyna;Cokot, Maria;Jozwiak, Andrzej;Klys, Arkadiusz. And the article was included in Journal of Molecular Liquids in 2020.Recommanded Product: 112-49-2 This article mentions the following:
The enthalpies of solution of monoglyme, diglyme, triglyme, tetraglyme, pentaglyme and hexaglyme in N,N-dimethylforamide+propan-1-ol mixtures have been measured at 298.15 K. The preferential solvation process of glymes mols. in the mixtures of N,N-dimethylformamide with methanol or propan-1-ol has been discussed. Then the contribution of DMF, PrOH, and MeOH to the solvation enthalpy of group (-CH2- and -O-) of glymes has been calculated On the basis of the obtained data, the effect of the structural and energetic properties of the N,N-dimethylforamide+propan-1-ol mixtures on the solution enthalpy of glymes in this mixtures has been analyzed. In the experiment, the researchers used many compounds, for example, 2,5,8,11-Tetraoxadodecane (cas: 112-49-2Recommanded Product: 112-49-2).
2,5,8,11-Tetraoxadodecane (cas: 112-49-2) belongs to ethers. Of all the functional groups, ethers are the least reactive ones. Ether bonds are quite stable towards bases, oxidizing agents and reducing agents. But on the other hand, ethers undergo cleavage by reaction with acids. Electron-deficient reagents are also stabilized by ethers. For example, borane (BH3) is a useful reagent for making alcohols. Pure borane exists as its dimer, diborane (B2H6), a toxic gas that is inconvenient and hazardous to use. Borane forms stable complexes with ethers, however, and it is often supplied and used as its liquid complex with tetrahydrofuran (THF).Recommanded Product: 112-49-2
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem