Synthetic Routes to Crystalline Complex Metal Alkyl Carbonates and Hydroxycarbonates via Sol-Gel Chemistry-Perspectives for Advanced Materials in Catalysis was written by Hanf, Schirin;Lizandara-Pueyo, Carlos;Emmert, Timo Philipp;Jevtovikj, Ivana;Glaeser, Roger;Schunk, Stephan Andreas. And the article was included in Catalysts in 2022.Recommanded Product: 2-(2-Methoxyethoxy)ethanol This article mentions the following:
Metal alkoxides are easily available and versatile precursors for functional materials, such as solid catalysts. However, the poor solubility of metal alkoxides in organic solvents usually hinders their facile application in sol-gel processes and complicates access to complex carbonate or oxidic compounds after hydrolysis of the precursors. In our contribution we have therefore shown three different solubilization strategies for metal alkoxides, namely the derivatization, the hetero-metalization and CO2 insertion. The latter strategy leads to a stoichiometric insertion of CO2 into the metal-oxygen bond of the alkoxide and the subsequent formation of metal alkyl carbonates. These precursors can then be employed advantageously in sol-gel chem. and, after controlled hydrolysis, result in chem. defined crystalline carbonates and hydroxycarbonates. Cu- and Zn-containing carbonates and hydroxycarbonates were used in an exemplary study for the synthesis of Cu/Zn-based bulk catalysts for methanol synthesis with a final comparable catalytic activity to com. standard reference catalysts. In the experiment, the researchers used many compounds, for example, 2-(2-Methoxyethoxy)ethanol (cas: 111-77-3Recommanded Product: 2-(2-Methoxyethoxy)ethanol).
2-(2-Methoxyethoxy)ethanol (cas: 111-77-3) belongs to ethers. The oxygen atom in ethers are more electronegative than carbon, thus the hydrogens which are alpha to the ethers are more acidic than the simple hydrocarbons. At room temperature, ethers are pleasant-smelling colourless liquids. Relative to alcohols, ethers are generally less dense, are less soluble in water, and have lower boiling points. They are relatively unreactive, and as a result they are useful as solvents for fats, oils, waxes, perfumes, resins, dyes, gums, and hydrocarbons. Vapours of certain ethers are used as insecticides, miticides, and fumigants for soil.Recommanded Product: 2-(2-Methoxyethoxy)ethanol
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem