Zhang, Shuxiang published the artcileSynthesis, characterization and properties of a novel fluorinated methacrylate polymer, Product Details of C4H7F3O2, the publication is Journal of Fluorine Chemistry (2011), 132(11), 915-919, database is CAplus.
A fluorinated monomer of 2-(2,2,2-trifluoroethoxy)ethyl methacrylate (FEMA) was prepared by a “one pot” process and then a novel fluorinated methacrylate polymer, poly[2-(2,2,2-trifluoroethoxy)ethyl methacrylate] (PFEMA), was successfully synthesized via miniemulsion polymerization using cetyltrimethyl ammonium bromide (CTAB) as emulsifier, hexadecane (HD) as co-stabilizer and 2,2′-azobisisobutyronitrile (AIBN) as initiator. The chem. structure of PFEMA was characterized by FT-IR, 1H NMR and 19F NMR. GPC results show that the number average mol. weight (Mn) of PFEMA was as high as 8.5 × 105 g/mol and the polydispersity index (PDI) was only 1.3. SEM and DLS characterizations showed that the morphol. of PFEMA latex was uniform spheres with the diameter of about 110-125 nm. It was also found that PFEMA has high thermo-stability (Td > 200 °C), low glass transition temperature (Tg = 13.0 °C), and nice hydrophobicity (θwater = 99.9°). Comparison studies on PFEMA and poly(2,2,2-trifluoroethyl methacrylate) show that an introduced functional group (-CH2CH2O-) has a significant effect on lowering Tg and improving hydrolysis resistance without impairing surface properties.
Journal of Fluorine Chemistry published new progress about 2358-54-5. 2358-54-5 belongs to ethers-buliding-blocks, auxiliary class Trifluoromethyl,Fluoride,Aliphatic hydrocarbon chain,Alcohol,Ether, name is 2-(2,2,2-Trifluoroethoxy)ethanol, and the molecular formula is C9H22OSi, Product Details of C4H7F3O2.
Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem