Brey, Mary L.'s team published research in Journal of the American Chemical Society in 79

Brey, Mary L. published the artcilePreparation and properties of some vinyl and glycidyl fluoro ethers, SDS of cas: 2358-54-5, the publication is Journal of the American Chemical Society (1957), 6533-6, database is CAplus.

KOH (94 g.) in 500 cc. (CH₂OH)₂ in an autoclave chilled with Dry Ice-Me₂CO, treated with approx. 2.5 moles of the appropriate 1,1-difluoronolefin, rocked at room temperature overnight, poured into iced H₂O, and the organic layer washed, dried, and distilled yielded the corresponding glycol monoether; in this manner were prepared the following ROCH₂CH₂OH (R, % yield, b.p./mm., n²⁵_D, d₂₅, and MR_D given): CHClFCF₂, 54, 114-18°/100, 1.3795/21°, -, -; CHCl₂CF₂ (I), 30, 62-3°/2, 1.4245, 1.4905, 33.42; CF₃CHFCF₂, 25, 72-4°/40, 1.3192, 1.5227, 27.57. As a by-product of I was also obtained 18% (CHCl₂CH₂OCH₂)₂, b_2.2 90°, n²⁵_D5 1.4194, d₂₅ 1.5786, MR_D 52.50, hydrolyzed with concentrated H₂SO₄ to 31% (CHCl₂CO₂CH₂)₂, b₃ 148-50°, n²⁵_D 1.4840, d₂₅ 1.5386, MR_D 52.79. KOH (5.0 g.) in 1.5 moles of the appropriate fluoro alc. treated in an autoclave at -78° with 44 g. ethylene oxide, rocked 4 hrs. at 70°, and worked up gave the corresponding glycol monoether; in this manner were prepared the following ROCH₂CH₂OH (same data as above given): CF₃CH₂, 50, 84°/80, 1.3502, 1.2902, 24.04; C₂F₅CH₂, 32, 87°/84, 1.3370, 1.3806, 29.24; C₃F₇CH₂, 62, 91-2°/54, 1.3300/28°, 1.4965/28°, 33.90; CF₃CMe₂, 35, 92°/77, 1.3749/22°, 1.1931/22°, 33.02. The appropriate fluoroalkyl hydroxyethyl ether (about 0.25 mole) treated with stirring with 60 g. PCl₅ in portions, refluxed 20 min., cooled, poured into iced H₂O, washed, dried, and fractionated yielded the corresponding compounds RO(CH₂)₂Cl (II) consistently in 27% yield; when the reaction mixture was diluted with about 100 cc. CHCl₃ the yields were 45-67%. In this manner were prepared the following II (same data given): CHClFCF₂ (III), 27, 85°/100, 1.3882, 1.4471, -; CHCl₂CF₂ (IV), 27, 86-7°/33, 1.4270, 1.4833, 36.95; CF₃CHFCF₂, 27, 46°/37, 1.3349, 1.4749, 32.33; CF₃CH₂, 53, 114-15°/760, 1.3590/27°, 1.3034/27°, 27.46; C₃F₇CH₂, 67, 75°/80, 1.3381, 1.4673, 37.32; CF₃CMe₂, 45, 135°/760, 1.3784, 1.2102, 36.34; C₂F₅CH₂, 49, 120-1°/760, 1.3448/26°, 1.3792/26°, 32.72. Hydrolysis of III yielded 34% CH₂ClCH₂O₂CHClF, b₄₇ 106°, b₄₅ 105°, n²³_D 1.4369, d₂₅ 1.4256, MR_D 32.20; IV gave similarly 36% CHCl₂CO₂(CH₂)₂Cl, b₇₆₀ 207-11°, n²⁵_D 1.4716, d₂₅ 1.4544, MR_D 36.85. The appropriate II (0.20 mole) treated dropwise with stirring and heating with 18 g. KOH in 120 cc. PrOH, the distillate poured into H₂O, and the organic layer washed, dried, and distilled yielded the corresponding compounds ROCH:CH₂ (same data given): CHClFCF₂, 52, 71-3°/760, 1.3531, 1.2408, -; CF₃CH₂, 32, 42-8°/760, 1.3180/27°, 1.118/ 27°, -; C₂F₅CH₂, 21, 54-60°/760, 1.3131/27°, 1.227/27°, 27.92; C₃F₇CH₂, 18, 78-82°/760, 1.3118/26°, 1.343/26°, 31.08. The appropriate fluoro alc. (0.50 mole) and 46 g. epichlorohydrin added to 25 g. NaOH in 300 cc. cold H₂O kept at room temperature overnight, and the organic layer worked up gave mixtures of the epoxy ether and the diether. CF₃CH₂OH gave in this manner 31% CF₃CH₂OCH₂CH.CH₂.O, b₇₆₀ 132-5°, n²⁵_D 1.3560, d₂₅ 1.2666, MR_D 26.93, and 19% (CF₃CH₂OCH₂)₂CHOH, b₁₆ 86°, n²⁵_D 1.3528, d₂₅ 1.3890, MR_D 39.97. C₂F₅CH₂OH gave similarly 19% C₂F₅CH₂OCH₂CH.CH₂.O, b_86-84 81-79°, n²⁵_D 1.3419, d₂₅ 1.3534, MR_D 32.08. C₃F₇CH₂OH gave 23% C₃F₇CH₂OCH₂CH.CH₂.O, b₄₉ 79°, n²⁵_D 1.3350, d₂₅ 1.4429, and 24% (C₃F₇CH₂OCH₂)₂CHOH, b₁₅ 112-15°, n²⁵_D 1.3338, d₂₅ 1.5569, MR_D 60.40. CF₃CH₂OH (100 g.), 185 g. epichlorohydrin, and 2 cc. pyridine heated 12 hrs. with stirring at 80-90° gave 50% CF₃CH₂OCH₂CH(OH)CH₂Cl, b₁₉ 85-6°, n²⁵_D 1.3951, d₂₅ 1.3716, MR_D 1.3716.

Journal of the American Chemical Society published new progress about 2358-54-5. 2358-54-5 belongs to ethers-buliding-blocks, auxiliary class Trifluoromethyl,Fluoride,Aliphatic hydrocarbon chain,Alcohol,Ether, name is 2-(2,2,2-Trifluoroethoxy)ethanol, and the molecular formula is C4H7F3O2, SDS of cas: 2358-54-5.

Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem