Sun, Huikai’s team published research in Organic Syntheses in 88 | CAS: 99438-28-5

Organic Syntheses published new progress about 99438-28-5. 99438-28-5 belongs to ethers-buliding-blocks, auxiliary class Chiral,Aliphatic cyclic hydrocarbon, name is (+)-B-Methoxydiisopinocampheylborane, and the molecular formula is C28H41N2P, Application In Synthesis of 99438-28-5.

Sun, Huikai published the artcileSynthesis of (+)-B-allyldiisopinocampheylborane and its reaction with aldehydes, Application In Synthesis of 99438-28-5, the publication is Organic Syntheses (2011), 87-101, database is CAplus and MEDLINE.

(+)-B-allyldiisopinocampheylborane (I) was prepared from (+)-B-methoxydiisopinocampheylborane and allylmagnesium bromide. Allylboration of achiral aldehydes by I gave secondary homoallylic alcs. stereoselectively. E.g., reaction of I and MeCHO gave 74% alc. (II). Allylboration of chiral aldehydes was also studied.

Organic Syntheses published new progress about 99438-28-5. 99438-28-5 belongs to ethers-buliding-blocks, auxiliary class Chiral,Aliphatic cyclic hydrocarbon, name is (+)-B-Methoxydiisopinocampheylborane, and the molecular formula is C28H41N2P, Application In Synthesis of 99438-28-5.

Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem