Prakash, Govindan published the artcileHeteroleptic binuclear copper(I) complexes bearing bis(salicylidene)hydrazone ligands: Synthesis, crystal structure and application in catalytic N-alkylation of amines, Category: ethers-buliding-blocks, the publication is Polyhedron (2015), 62-69, database is CAplus.
A new series of heteroleptic binuclear Cu(I) bis(salicylidene)hydrazone complexes (1–4) bearing triphenylphosphine coligands have been synthesized from the reactions of copper(II) precursor complex [CuCl2(PPh3)2] with oxadiazole compounds A-D, resp. It has been observed that the oxadiazole compounds undergo ring cleavage with in situ reduction of Cu(II) ion, during the formation of complexes (1–4). The oxadiazoles (A-D) and the Cu(I) complexes (1–4) have been characterized by anal. and spectroscopic methods. Single crystal x-ray diffraction study of complex 2 revealed a distorted tetrahedral geometry around each Cu(I) center. Catalytic efficiency of the new complexes on the N-alkylation of amines using alcs. was studied under optimized conditions. The new complexes have also been tested for their catalytic activity towards the direct N-alkylation of 2-nitropyridine.
Polyhedron published new progress about 52818-63-0. 52818-63-0 belongs to ethers-buliding-blocks, auxiliary class Pyridine,Amine,Benzene,Ether, name is N-(4-Methoxybenzyl)pyridin-2-amine, and the molecular formula is C13H14N2O, Category: ethers-buliding-blocks.
Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem