McDonald, Frank E. published the artcileStereo- and regioselective synthesis of 2-amino-3,5-diols via stereospecific crotyl transfer and regioselective aminohydroxylation, SDS of cas: 99438-28-5, the publication is Synthesis (2012), 44(23), 3639-3648, database is CAplus.
A short synthesis of 2-amino-3,5-diols is described, including the all-S isomer enigmol, a synthetic anticancer compound inspired by the structure of fumonisin B1. The synthetic route features stereospecific crotyl transfer to tetradecanal via pericyclic oxonia-Cope rearrangement; stereoselective epoxidation of the alkene; regioselective epoxide opening with azide; and reduction of azide to amine. This manuscript also corrects a structure assignment error in a previously reported synthesis of one of the diastereomers of enigmol.
Synthesis published new progress about 99438-28-5. 99438-28-5 belongs to ethers-buliding-blocks, auxiliary class Chiral,Aliphatic cyclic hydrocarbon, name is (+)-B-Methoxydiisopinocampheylborane, and the molecular formula is C21H37BO, SDS of cas: 99438-28-5.
Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem