Jacquesy, Rose’s team published research in Bulletin de la Societe Chimique de France in | CAS: 2944-47-0

Bulletin de la Societe Chimique de France published new progress about 2944-47-0. 2944-47-0 belongs to ethers-buliding-blocks, auxiliary class Benzene,Ether, name is 2-Isopropylanisole, and the molecular formula is C10H14O, Related Products of ethers-buliding-blocks.

Jacquesy, Rose published the artcileIsomerization and oxidation of simple ketones in superacid medium, Related Products of ethers-buliding-blocks, the publication is Bulletin de la Societe Chimique de France (1978), 255-62, database is CAplus.

Treatment of cyclohexanones having a tertiary C α or β to the CO group, e.g., carvomenthone (I, R = Me, Z = O, Z1 = H2), menthone(I, R = Me, Z = H2, Z1 = O), I (R = H, Z = H2 Z1 =O) with HF-SbF5 gave the isomerization, ring contraction, or dehydrogenation derivatives, e.g., II (R1-R4 = Me, Et, Me, H; H, Me, H,CHMe2), III, IV (R5-R8 = H, CH2CHMe2, H, Me; Me, CHMe2, Me, H; H, Me H, CHMe2 via protonation of the O whereas 3-methyl- and 3,3,5-trimethylcyclohexanone did not react with the acids. However, in cyclohexenones, dehydrogenation occurred only if the product was stable, e.g., V (R9 = H, R10 = CHMe2) dehydrogenated with HF-SbF5 to give the conjugated VI whereas with V (R9 = R10 = Me; R9 = H, R10 = Et) no dehydrogenation products were obtained.

Bulletin de la Societe Chimique de France published new progress about 2944-47-0. 2944-47-0 belongs to ethers-buliding-blocks, auxiliary class Benzene,Ether, name is 2-Isopropylanisole, and the molecular formula is C10H14O, Related Products of ethers-buliding-blocks.

Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem