Huh, Chan Woo published the artcileHighly Stereoselective and Modular Syntheses of 10-Hydroxytrilobacin and Three Diastereomers via Stereodivergent [3 + 2]-Annulation Reactions, Category: ethers-buliding-blocks, the publication is Organic Letters (2008), 10(15), 3371-3374, database is CAplus and MEDLINE.
A convergent synthesis of the annonaceous acetogenin, 10-hydroxytrilobacin (I), was accomplished by using the [3+2]-annulation reaction of tetrahydrofuranyl carboxaldehyde II and allylsilane III. The stereodivergency of the [3+2]-annulation reaction made it possible to achieve modular, highly stereoselective syntheses of three 10-hydroxytrilobacin diastereomers from the same precursors by using simple modifications of reaction conditions.
Organic Letters published new progress about 99438-28-5. 99438-28-5 belongs to ethers-buliding-blocks, auxiliary class Chiral,Aliphatic cyclic hydrocarbon, name is (+)-B-Methoxydiisopinocampheylborane, and the molecular formula is C21H37BO, Category: ethers-buliding-blocks.
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Ether | (C2H5)2O – PubChem