Ge, Chenyang published the artcileUnsymmetrical indazolyl-pyridinyl-triazole ligand-promoted highly active iridium complexes supported on hydrotalcite and its catalytic application in water, Formula: C13H14N2O, the publication is Green Chemistry (2018), 20(8), 1805-1812, database is CAplus.
Herein, an indazolyl-pyridinyl-triazole ligand was synthesized and its Ir complex supported on hydrotalcite was characterized via x-ray power diffraction (XRD), XPS, energy dispersive X-ray (EDX) spectroscopy and TEM. This new heterogeneous catalyst bearing the unsym. indazolyl-pyridinyl-triazole ligand exhibits high catalytic activity in H2O. Both functionalized amines and imines were obtained from the challenging selective reaction of benzylamines with arylamines through transfer hydrogenation and dehydrogenation under clean conditions. In particular, this catalyst system showed good recovery performance in H2O. Mechanistic studies showed that this transformation occurs via amine dehydrogenation, hydrolysis and condensation processes. The direct capture of the reaction intermediate provides sufficient proof for this process.
Green Chemistry published new progress about 52818-63-0. 52818-63-0 belongs to ethers-buliding-blocks, auxiliary class Pyridine,Amine,Benzene,Ether, name is N-(4-Methoxybenzyl)pyridin-2-amine, and the molecular formula is C13H14N2O, Formula: C13H14N2O.
Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem