Fuwa, Haruhiko published the artcileTotal Synthesis, Stereochemical Reassignment, and Biological Evaluation of (-)-Lyngbyaloside B, Computed Properties of 99438-28-5, the publication is Angewandte Chemie, International Edition (2015), 54(3), 868-873, database is CAplus and MEDLINE.
(-)-Lyngbyaloside B is a 14-membered macrolide glycoside isolated from the marine cyanobacterium Lyngbya sp. as a cytotoxic substance by Moore and co-workers. The first total synthesis of (-)-lyngbyaloside B and the reassignment of its stereo-structure is described. The synthesis features an Abiko-Masamune aldol reaction, a vinylogous Mukaiyama aldol reaction, and a macrocyclization involving an acyl ketene intermediate for the construction of the macrocyclic backbone, which contains an acylated tertiary alc. The antiproliferative activity of selected compounds against a small panel of human cancer cell lines is also reported.
Angewandte Chemie, International Edition published new progress about 99438-28-5. 99438-28-5 belongs to ethers-buliding-blocks, auxiliary class Chiral,Aliphatic cyclic hydrocarbon, name is (+)-B-Methoxydiisopinocampheylborane, and the molecular formula is C21H37BO, Computed Properties of 99438-28-5.
Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem