Bowie, John H.’s team published research in Journal of the Chemical Society [Section] B: Physical Organic in | CAS: 2944-47-0

Journal of the Chemical Society [Section] B: Physical Organic published new progress about 2944-47-0. 2944-47-0 belongs to ethers-buliding-blocks, auxiliary class Benzene,Ether, name is 2-Isopropylanisole, and the molecular formula is C10H14O, Product Details of C10H14O.

Bowie, John H. published the artcileSolvent effects in nuclear magnetic resonance spectroscopy. X. Solvent shifts induced by benzene in ortho-and meta-substituted methoxybenzenes, Product Details of C10H14O, the publication is Journal of the Chemical Society [Section] B: Physical Organic (1967), 535-40, database is CAplus.

Solvent shifts (Δ = δCCl4-δC6H6 ppm.) for the methoxyl protons of meta-substituted anisoles correlate with σm of the substituent, but for ortho-substituted anisoles a better correlation between Δ and the dipole moment is found. The effect of introducing a methoxyl group ortho to a substituent in a benzene ring is to make the Δ values for protons in that substituent more neg. In the compounds examined, protons α to the benzene ring (Ar-CH) and attached to a substituent situated between two o-methoxyl groups are only shielded (0.4-0.6 ppm.) in benzene relative to CCl4. On the basis of the observed shifts the orientating effect of an aromatic methoxyl function in a solute upon benzene solvent mols. may be surmised.

Journal of the Chemical Society [Section] B: Physical Organic published new progress about 2944-47-0. 2944-47-0 belongs to ethers-buliding-blocks, auxiliary class Benzene,Ether, name is 2-Isopropylanisole, and the molecular formula is C10H14O, Product Details of C10H14O.

Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem