Berkowitz, Alex J. published the artcileSynthesis of α-Tropolones through Autoxidation of Dioxole-Fused Cycloheptatrienes, Name: 1,2-Dimethoxybenzene, the publication is Journal of Organic Chemistry (2022), 87(7), 4499-4507, database is CAplus and MEDLINE.
Herein, we describe the formation of tropolones through the autoxidation of Buchner reaction-derived cycloheptatrienes. The reaction is exceptionally simple procedurally, as it involves blowing a stream of compressed air over the cycloheptatriene, and the products can be obtained without any need for chromatog. The chem. works specifically on dioxolane-fused systems or close variants, and substitution patterns are also important. A radical-based mechanistic hypothesis is put forward to explain these results. Finally, we demonstrate the utility of the overall process in the synthesis of amide-appended tropolones and an isomer of stipitatic acid.
Journal of Organic Chemistry published new progress about 91-16-7. 91-16-7 belongs to ethers-buliding-blocks, auxiliary class Benzene,Ether,Inhibitor,Inhibitor,Inhibitor, name is 1,2-Dimethoxybenzene, and the molecular formula is C8H10O2, Name: 1,2-Dimethoxybenzene.
Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem