Inomata, Koya published the artcileRuthenium-catalyzed selective hydrosilylation reaction of allyl-functionalized PEG derivatives, Formula: C9H20O5, the main research area is polyethylene glycol allyl ether derivative ruthenium catalyzed selective hydrosilylation.
Reactions of allyl-functionalized poly(ethylene glycol) (PEG) derivatives with alkoxysilanes proceeded efficiently to furnish the corresponding hydrosilylated products in good to excellent yields using a ruthenium catalyst, [RuCl2(nbd)]n. A preliminary mechanistic study supported the pivotal role of the PEG moiety, which coordinated to the ruthenium atom during the reaction to achieve high reaction selectivity. This method may be applicable to the synthesis of various PEGs with a silyl terminus, which is useful as biocompatible and low toxic silane coupling agents.
Tetrahedron Letters published new progress about Hydrogenation. 23783-42-8 belongs to class ethers-buliding-blocks, name is 2,5,8,11-Tetraoxatridecan-13-ol, and the molecular formula is C9H20O5, Formula: C9H20O5.
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem