Celik Kucuk, Asuman published the artcileEffects of LiBOB on salt solubility and BiF3 electrode electrochemical properties in fluoride shuttle batteries, Quality Control of 143-24-8, the main research area is bismuth fluoride lithium bisoxalatoborate salt electrode electrochem shuttle battery.
In this study, lithium bis(oxalato)borate (LiBOB) was used for the first time in a fluoride shuttle battery (FSB) to overcome the solubility problem of fluorine-based salts typically present in organic solvents. For this purpose, tetraglyme (G4) electrolytes containing CsF salt and LiBOB with three different concentrations (LiBOB0.06/CsF/G4, LiBOB0.25/CsF/G4, and LiBOB0.5/CsF/G4) were prepared The effects of LiBOB on the electrochem. compatibility of the bismuth fluoride pos. electrode were examined by cyclic voltammetry, charge-discharge tests, and a.c. impedance measurements. The related discharge and charge reactions were confirmed by X-ray diffractometry, whereas 19F NMR and Raman spectroscopies were used to detect potential interactions in the various LiBOB/CsF/G4 systems. At the lowest and highest LiBOB concentrations (i.e., in LiBOB0.06/CsF/G4 and LiBOB0.5/CsF/G4, resp.), the electrolyte decomposition was dominant, whereas the intermediate concentration in LiBOB0.25/CsF/G4 was found to be the optimum condition and played a critical role in CsF solubility, allowing a successful fluoride shuttle-based redox reaction.
Journal of Materials Chemistry A: Materials for Energy and Sustainability published new progress about Battery cathodes. 143-24-8 belongs to class ethers-buliding-blocks, name is 2,5,8,11,14-Pentaoxapentadecane, and the molecular formula is C10H22O5, Quality Control of 143-24-8.
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem