Zhou, Jun published the artcileEtherification of Fluoroarenes with Alkoxyboronic Acid Pinacol Esters via C-F Bond Cleavage, Synthetic Route of 91-16-7, the publication is Organic Letters (2022), 24(28), 5084-5089, database is CAplus and MEDLINE.
Potassium-base-mediated defluoroetherification of aryl and heteroaryl fluorides with alkoxyboronic acid pinacol esters under transition-metal-free conditions is reported. This protocol efficiently and safely provides a wide variety of aryl ethers in high yields without using metal catalysts, specific ligands, and harsh conditions to selectively forge Csp2-O bonds via the Csp2-F cleavage. This method can be applied to the late-stage etherification of structurally complex Csp2-fluorides and bioactive alcs., such as β-estradiol, calciferol, and tocopherol.
Organic Letters published new progress about 91-16-7. 91-16-7 belongs to ethers-buliding-blocks, auxiliary class Benzene,Ether,Inhibitor,Inhibitor,Inhibitor, name is 1,2-Dimethoxybenzene, and the molecular formula is C11H22N2O4, Synthetic Route of 91-16-7.
Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem