Yang, Shaoxiong published the artcileModulating the Stacking Model of Covalent Organic Framework Isomers with Different Generation Efficiencies of Reactive Oxygen Species, Name: (2-Methoxyphenyl)methanamine, the publication is ACS Applied Materials & Interfaces (2021), 13(25), 29471-29481, database is CAplus and MEDLINE.
The development of a facile synthesis and controllable layer stacking approach for covalent organic frameworks (COFs) is an important issue for modulating their properties and realizing their application diversity. Herein, three COF isomers with different stacking models (eclipsed AA, staggered AB, and ABC stacking) were obtained by modulating the reaction temperature and solvent medium. Exptl. and theor. calculations show that the ABC stacking isomer obtained at room temperature is the kinetic product, while the AA stacking isomer prepared by the solvothermal method is a thermodn. product. Owing to the tautomerism involved in the reaction process, these isomers possess different ratios of enol and keto forms. Thus, they exhibit different generation efficiencies of Type I and Type II reactive oxygen species (ROS). The ABC stacking isomers could be employed as metal-free heterogeneous photocatalysts for visible-light-induced oxidation of amines to imines, owing to the highest generation efficiency of Type I ROS.
ACS Applied Materials & Interfaces published new progress about 6850-57-3. 6850-57-3 belongs to ethers-buliding-blocks, auxiliary class Amine,Benzene,Ether, name is (2-Methoxyphenyl)methanamine, and the molecular formula is C4H10Br2CoO2, Name: (2-Methoxyphenyl)methanamine.
Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem