Chen, Kang published the artcileCobalt-Mediated Decarboxylative/Desilylative C-H Activation/Annulation Reaction: An Efficient Approach to Natural Alkaloids and New Structural Analogues, SDS of cas: 6850-57-3, the publication is European Journal of Organic Chemistry (2022), 2022(16), e202101355, database is CAplus.
A Co(II)-mediated decarboxylative/desilylative C-H activation/annulation reaction for the efficient synthesis of 3-arylisoquinolines has been developed [e.g., N-benzylpicolinamide + phenylpropiolic acid â?3-phenylisoquinoline (86%) in presence of Co(OAc)2 as catalyst, KPF6 as additive and PEG-400 as solvent; an 80% yield was obtained using 1-phenyl-2-(trimethylsilyl)acetylene instead, under the same optimized conditions.]. Using alkynyl carboxylic acid and alkynyl silane as terminal alkyne precursors provides straightforward routes for the synthesis of natural alkaloids and novel structural analogs.
European Journal of Organic Chemistry published new progress about 6850-57-3. 6850-57-3 belongs to ethers-buliding-blocks, auxiliary class Amine,Benzene,Ether, name is (2-Methoxyphenyl)methanamine, and the molecular formula is C8H11NO, SDS of cas: 6850-57-3.
Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem