Barrett, Anthony G. M. published the artcileB-[3-((Diisopropylamino)dimethylsilyl)allyl]diisopinocampheylborane: an excellent reagent for the stereoselective synthesis of anti vicinal diols, Recommanded Product: (+)-B-Methoxydiisopinocampheylborane, the publication is Journal of Organic Chemistry (1991), 56(18), 5243-5, database is CAplus.
Title reagent I, derived from (+)-α-pinene, reacted with aldehydes to provide, on work up with hydrogen peroxide, (3S,4R)-dihydroxy-1-alkenes. These were formed with both high relative and absolute stereochem. control. The antipodal reagent, derived from (-)-α-pinene, gave the corresponding (3R,4S)-diols.
Journal of Organic Chemistry published new progress about 99438-28-5. 99438-28-5 belongs to ethers-buliding-blocks, auxiliary class Chiral,Aliphatic cyclic hydrocarbon, name is (+)-B-Methoxydiisopinocampheylborane, and the molecular formula is C21H37BO, Recommanded Product: (+)-B-Methoxydiisopinocampheylborane.
Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem