Rochette, Etienne published the artcileIsodesmic C-H Borylation: Perspectives and Proof of Concept of Transfer Borylation Catalysis, Formula: C11H17BO3S, the publication is Journal of the American Chemical Society (2019), 141(31), 12305-12311, database is CAplus and MEDLINE.
The potential advantages of using arylboronic esters as B source in the C-H borylation are discussed. The concept is showcased by using com. available 2-mercaptopyridine as a metal-free catalyst for the transfer borylation of heteroarenes, using arylboronates as borylation agents. The catalysis shows a unique functional group tolerance among C-H borylation reactions, tolerating notably terminal alkene and alkyne functional groups. The computational study of the mechanism is also described.
Journal of the American Chemical Society published new progress about 596819-12-4. 596819-12-4 belongs to ethers-buliding-blocks, auxiliary class Thiophene,Boronic acid and ester,Ether,Boronate Esters,Boronic acid and ester, name is 2-(5-Methoxythiophen-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane, and the molecular formula is C11H17BO3S, Formula: C11H17BO3S.
Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem