Renaud, J. L. published the artcileRuthenium-catalysed enantioselective hydrogenation of trisubstituted enamides derived from 2-tetralone and 3-chromanone: Influence of substitution on the amide arm and the aromatic ring, Product Details of C3H7NO2, the publication is Advanced Synthesis & Catalysis (2003), 345(1+2), 230-238, database is CAplus.
Cyclic enamides, e.g. I, were prepared in one step from tetralone and chromanone derivatives and primary amides under acidic conditions. The enantioselective hydrogenation of these enamides bearing an endocyclic trisubstituted carbon-carbon double bond was performed at room temperature in the presence of ruthenium catalysts. The nature of the amide group had little influence on the enantioselectivity of the hydrogenation when mononuclear precatalysts were used. The presence of a coordinating atom at some specific position on the tetralone and chromanone skeleton led to a dramatic decrease of the enantiomeric excesses.
Advanced Synthesis & Catalysis published new progress about 16332-06-2. 16332-06-2 belongs to ethers-buliding-blocks, auxiliary class Amine,Aliphatic hydrocarbon chain,Amide,Ether, name is 2-Methoxyacetamide, and the molecular formula is C3H7NO2, Product Details of C3H7NO2.
Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem