Kushawaha, Ajay Kishor published the artcileA simple and efficient oxidation of primary and secondary benzylamines to acids using table salt in aqueous medium, Related Products of ethers-buliding-blocks, the publication is Tetrahedron (2021), 132502, database is CAplus.
A novel, simple, efficient method for the oxidation of aromatic benzylamines RCH2NH2 (R = C6H5, 4-FC6H4, 2-thienyl, etc.), R1CH2NHCH2R1 (R1 = C6H5, 4-ClC6H4, 2-thienyl, etc.) and 4-OCH3C6H4CH2NHR2 (R2 = Me, Et, Pr, n-octyl, t-butyl) to corresponding acids RC(O)OH, R1C(O)OH and 4-methoxybenzoic acid using common table salt in aqueous medium has been described. Oxidation of benzylamine was achieved by using NaCl (20 mol%) as a catalyst, NaOH (4 equiv) and TBHP (5 equiv) as oxidant, in moderate to good yields (34-84%). Control experiments revealed that in situ generated ClO2– ion is the active form of the catalyst. This methodol. can also be scaled up for easy accessibility to the industrially important terephthalic acid as well. This investigation provided a facile entry of various primary as well as secondary benzylamines with wide range of functional group tolerance.
Tetrahedron published new progress about 6850-57-3. 6850-57-3 belongs to ethers-buliding-blocks, auxiliary class Amine,Benzene,Ether, name is (2-Methoxyphenyl)methanamine, and the molecular formula is C8H11NO, Related Products of ethers-buliding-blocks.
Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem