Bolton, Peter D. published the artcileHydrolysis of amides. V. Alkaline hydrolysis of alkyl-substituted amides, COA of Formula: C3H7NO2, the publication is Australian Journal of Chemistry (1971), 24(5), 969-74, database is CAplus.
Enthalpies and entropies of activation were derived from rate constants measured over a range of temperature for the alk. hydrolysis of acetamide, propionamide, butyramide, n-valeramide, isovaleramide, phenylacetamide, cyclohexylacetamide, methoxyacetamide, cyclohex-anecarboxamide, cyclopentane carboxamide, α-methylbutyramide, isobutyramide, and trimethylacetamide. These results are discussed in terms of their correlation by Taft-type equations which were extended to incorporate a factor based upon the α-hydrogen bond concept of hyperconjugative stabilization. The rate constants of these 13 amides under these conditions appear to be governed by a combination of polar, steric, and hyperconjugative factors.
Australian Journal of Chemistry published new progress about 16332-06-2. 16332-06-2 belongs to ethers-buliding-blocks, auxiliary class Amine,Aliphatic hydrocarbon chain,Amide,Ether, name is 2-Methoxyacetamide, and the molecular formula is C3H7NO2, COA of Formula: C3H7NO2.
Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem